pH-Driven dynamic stereoinduction: epimerization upon dimerization in rhenium(I) complexes.
نویسندگان
چکیده
Stereochemistry at the metal centre in a Re(I) complex can be modified by manipulating the pH: while acidic conditions favour a monomeric system, basic conditions induce a dimerization which concomitantly epimerizes the metal centre.
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عنوان ژورنال:
- Chemical communications
دوره 47 48 شماره
صفحات -
تاریخ انتشار 2011